Ć First read the "Sun Essentials" article, click here ==>  SUN ESSENTIALS by Paula Begoun

 Reference:  Begoun, Paula. Sun essentials. Paula Begoun The Cosmetics Cop.
http://www.cosmeticscop.com/sun-care-essentials.aspx
(November 2008). 

 Ć Then see Dr. H's summarizing TABLE below, followed by her additional comments.

NOTE: Paula Begoun's site is a commercial site, but it has a very good summary of some key information that is difficult to find elsewhere. (Begoun, aka the "Cosmetics Cop"  has spent her career examining the scientific basis underlying the ingredients and performance claims of thousands of skin care products.  Read more about her to evaluate her trustworthiness as a source for yourself HERE)

Click here for more useful info from Paula Begoun


From Dr H:

The following TABLE was complied by Dr H based on a variety of sources including the Sun Essentials article linked above:

The range of protection for the following sunscreen ingredients is summarized in the following table:

 (Note that the boundaries of UVA, UVB & UVC differ slightly in different sources.  The UVA-UVB boundary is usually reported as 315 nanometers, but is rounded to 320 nm in the IGC text  & the UVB-UVC boundary is usually reported as 280 but is given as 290 nm in IGC Table 17-1.)

  UV wavelength bands

UVC

UVB

UVA

  wavelength band range in nanometers
according to IGC, Table 17-1 p 344

200-290
(100-280
 in other sources)

290-320
(280-315
 in other sources)

320-400
(315-400
in other sources)

 

 

Padimate O, 290-315 nanometers

 

(X)

 

Benzophenones, 250-350 nanometers

(X)

X

(X)

Octyl methoxycinnamate, 290-320 nanometers

 

X

 

Avobenzone, 320-400 nanometers

 

 

XX 

Oxybenzone 270 to 350 nanometers

(X)

X

(X)

Titanium dioxide, 290-700 nanometers

 

X

XX

Zinc oxide, 290-700 nanometers

 

X

XX

NEW! Ecamsule (Mexoryl SX ) ***
             max absorption 345 nm
 

X

XX

X means the ingredient protects over the entire band,
(X) means the ingredient protects over part of the band
XX means the ingredient protects over the longer wavelength UVA band, now known to be harmful

Check the active ingredients. Titanium dioxide, zinc oxide, or avobenzone (also called butyl methoxydibenzoylmethane) are the only***  ingredients authorized for use in U.S. products that protect you from the entire UVA spectrum. Therefore, if one of those isn't listed as an active ingredient on the label, the product should not be used for sun protection by anyone.


*** The following additional comments section was added by Dr H (on 9/8/06):
 

 
 

 

UVA PROTECTION UPDATE:

As of July 2006,the active ingredient ecamsule / Mexoryl SX / Anthelios SX (different names for same active ingredient or product including the active ingredient) has been approved in the U.S. and provides UVA protection. 

 For information on the importance of UVA protection see:

Sunscreens: The Importance of UVA Protection  [pdf] Medscape Today article 431185
Source: www.medscape.com

Comparison of UVA protection afforded by high sun protection factor sunscreens   [pdf]  Bissonette, et al. 2000. Journal of the American Academy of Dermatology v 43, Dec 2006 p 1036-1038 
(a fairly readable 3-page scientific article comparing sunscreen ingredients for UVA protection)
                
 
The article states:

In conclusion, labeled SPF is not predictive of UVA protection as assessed by pigmentation induced at 2 hours after exposure to UV radiation.  In addition to SPF, another labeling method to specifically compare UVA protection could help in sunscreen selection.  (p 1038)

*** PRESS RELEASES & NEWS STORIES On July 24, 2006 the FDA approved a new active ingredient that protects against UVA (and UVB) for use in the U.S. 

See the following links and press releases about this new active ingredient (which Dr H just added to the table above):

FDA Approves a New Over-the-Counter Sunscreen Product  FDA News  24 July 2006 Federal Drug Administration press release

Mexoryl SX An Ally for Sun Protection - L'Oreal promotional webpage (discusses wavelength range!)
FDA OKs New Sunscreen Anthelios SX Includes an Active Ingredient Previously Unmarketed in U.S.  WebMD 24 July 2006
Sunscreen that blocks rays tied to skin cancer approved  Arizona Republic 25 July 2006
Asked and Answered: Did I hear about a new kind of sunscreen?  Detroit Free Press  25 July 2006

 


 

 

For more information about sun care and sun care products:


More info from Paula Begoun:


 

APPLYING SUNSCREEN & THE EXTRA HAZARD OF HIGH ALTITUDES


http://www.cosmeticscop.com/bulletin/081105-full.htm#2

Dear Paula,
Thank you so much for revolutionizing my skin-care routine! Even though I have much faith in your research and your dedication to consumers, I keep getting hung up on the issue of sunscreens and how to use them. I keep reading that reapplying sunscreen is essential, usually every 2 hours. If a sunscreen with SPF 15 is designed to let me be out in the sun all day, why should I have to reapply? Do sunscreens lose their effectiveness on the skin after 2 hours (for example, if I apply at 8 a.m. but am not exposed to the sun until 4 p.m., will it still provide protection?), or is it depleted after 2 hours in the sun? Reapplying so often makes my skin feel too slick and laden with product, not to mention it disturbs my makeup.

Jesse, via email


Dear Jesse,
If you are spending long periods of time in the sun, especially under extreme sun exposure conditions, there is research showing that frequent application of sunscreen, every two hours as you mentioned, does have validity. According to information on the American Academy of Dermatology's Web site (www.aad.org), "a study followed 105 skiers in Vail, Colorado over a one-week period in January. Each participant was given an unmarked bottle of sunscreen (either SPF 15 or 30) and instructed to maintain a log of the amount of time they spent outdoors as well as the amount of sunscreen applied.... The study concluded sunscreen, when used correctly, was an effective defense from sunburn when in an open aired, highly elevated, sun exposed and sun reflective environment." However, those who applied the sunscreen after 2.5 hours or longer "were five times more likely to sunburn compared to those who applied sunscreen every two hours or more."

What is important to keep in mind about this information is that this study was done on skiers who were exposed to about 40% additional UV intensity than most people due to the reflection of sunlight off the snow. Also, "[UV] intensities at altitudes of 8,000 to 11,000 feet have been shown to be 60% to 80% higher than at sea level."

If you are not experiencing sun exposure under those conditions, you can follow the standard time guideline for an SPF rating, which is the SPF number multiplied by the amount of time you can usually be in the sun without burning (turning pink). For those with lighter skin tones, the formulas look like this-SPF 15 X 15 minutes = 225 minutes (or 3.75 hours) of protection or this-SPF 15 X 10 minutes = 150 minutes (2.5 hours) of protection. Whether or not that means continuous time in direct sun exposure or simply time of wear from the moment you apply sunscreen isn't clear. Having spoken to a number of dermatologists they each seem to have different opinions (even some who just said to "wear an SPF 50 and you'll be fine," which is bad advice because it doesn't address the issue of liberal application, UVA protection, and sun behavior). Even the FDA has varying explanations on its Web site.

Bottom line, it is without question safer to frequently apply a well-formulated sunscreen if you are planning to spend long periods of time exposed to the sun, especially if you aren't able to comply with other sun-smart behavior, such as avoiding deliberate tanning with indoor or outdoor light; seeking shade; wearing protective clothing; limiting exposure during peak hours; and covering up with hats, sunglasses, and UV-protective clothing whenever possible.


 

ON "WATERPROOF" SUNSCREENS

http://www.cosmeticscop.com/bulletin/072105-full.htm#review1

Dear Paula,
I have read from several sources that you should always use a water-proof sunscreen, and that anything that isn't water-proof is wasting your time and money. While I know that the label "waterproof" doesn't always mean "100% waterproof," I still wonder about this. Do lotions that contain a sunscreen but that are not water-proof really protect skin? When is water-proof appropriate and when is it not needed (if ever)? Up until now, I have always looked for water-proof sunscreens for daily use, but they tend to be thicker and more gooey than other types of sunscreens, and they don't sit well under my makeup. I have been hesitant to use anything else, however, because I want the best protection I can get. Help clear this up for me so I can enjoy my summer without feeling overly slathered!

Pamela, Rochester, New York


Dear Pamela,
I'm not sure where you got your information, but there are several problems with the advice that you need to wear only "waterproof" sunscreens. First, the term water-proof is no longer allowed by the FDA, so your sources obviously weren't well-informed. Water-proof was replaced with water-resistant and very water-resistant (the water- prefix in the previous terms can also be replaced by sweat- or perspiration-). This significant change in sunscreen regulations took place a few years ago because, in truth, no sunscreen can be water-proof. Eventually all sunscreens will break down and become ineffective when you become wet, whether from swimming, showering, sweating, or rinsing your hands. The sunscreens formulated to hold up under water immersion are time-limited, lasting up to 40 minutes for water-resistant and 80 minutes for very water-resistant (Source: Code of Federal Regulations, Title 21, volume 5, April 1, 2004, CITE: 21CFR352, www.fda.gov ). When you become wet, you must reapply sunscreen in a relatively short period of time.

A sunscreen designated as water-proof or water-resistant provides no added benefit over and above some amount of tenacity if you become wet. If you are not planning to exercise, swim, or in any other way become moist, there is no reason to use a water-resistant sunscreen or one mislabeled as water-proof. Regular sunscreens stay in place for the appropriate amount of time indicated by the SPF number. Personally, because I know my hands are in water frequently during the day while the rest of me stays dry, I do use a water-resistant sunscreen on my hands and arms.

One more point: while some water-resistant sunscreens do tend to feel a bit sticky on skin, there are definitely those that do not. You might want to experiment a bit to find one that has the texture you prefer. Regardless, the most important things to remember about sunscreens are: use an SPF 15 or greater (and greater can be better for long days of sunlight), apply it liberally (more is better), and check for the UVA-protecting ingredients of titanium dioxide, zinc oxide, or avobenzone (often listed as butyl methoxydibenzylmethane or Parsol 1789).

 


ON TANNING

 . . . . A recent survey of over 500 teens by the American Academy of Dermatology revealed that although 80% of them know tanning is dangerous and that sunburns increase the risk of skin cancer, the majority believe tans look healthier, and 60% of respondents reported getting a sunburn during the past summer (Source: ABC news Health wire story 7-20 -05 link no longer active:  http://abcnews.go.com/Health/wireStory?id=720505).

Dermatologists (and sunscreen advocates like me) are disappointed with this information, because it means that although teens seem to understand that tanning is dangerous, they opt to ignore the information for the sake of vanity. But don't give up! Please do whatever you can to impress on your teens that tanning beds are nothing more than cancer beds. The proliferation of tanning salons is believed to be partly responsible for the increase in the incidence of melanoma, the deadliest form of skin cancer, which has doubled in the past 30 years (Source: http://skin-savers.com/Information/Newsletter_-_March_2005/ ).

In related news, the Dermatology Nurses' Association agreed to support the World Health Organization's (WHO) proposed ban on sun-bed use for those under age 18. In March, WHO called for countries to enact laws to reinforce this protective measure, citing that most tanning-salon beds emit ultraviolet rays that are much more potent than the UV rays of the summer sun, and that the use of such tanning beds is incrementally increasing skin-cancer rates worldwide. In the United States, 22 states already have laws prohibiting underage tanning in salons (Source: Dermatology Nurses' Association press release, April 1, 2005). Actually, the Dermatology Nurses' Association, in response to the young patients with UV-damaged skin they see every day, have proposed an even stricter stance on tanning beds. To learn more, visit www.dnanurse.org .


ON THE VITAMIN D  CONTROVERSY

Paula Begoun Website:  see http://www.cosmeticscop.com/bulletin/031705-full.htm#5

 

Vitamin D and Sunscreen

It’s hard to imagine that a vitamin could find itself in the midst of a controversy, but that is exactly the position vitamin D is in. The conflict is over risking sun exposure because of our bodies’ need for vitamin D. Vitamin D deficiency can be a serious health problem, most notably by blocking the absorption of calcium and phosphorus, causing a chronic imbalance and bone deterioration. As luck would have it, sunlight is the most abundant, natural source that helps our bodies make vitamin D.

You may be unaware that, despite the name, vitamin D is not actually a vitamin. It is a hormone known as calcitrol. When your skin is exposed to UVB light, it converts 7-dehydrocholesterol (present in your skin and bloodstream) into vitamin D, where the liver and kidneys activate it and it begins regulating and enhancing the absorption of the minerals calcium and phosphorus in the body. Since there are very few foods that naturally contain vitamin D (your best options are salmon, mackerel, and cod liver oil) most of us need to rely on either sun exposure or vitamin D-fortified foods (such as milk and cereals) to ensure we get enough.

Where the controversy takes place is that exposing our skin to the sun without sunscreen is dangerous, but there are those that believe sunscreen will cancel out the body's ability to manufacture vitamin D from sun exposure. This concern has been expressed from several seemingly reputable resources (Sources: http://www.intelihealth.com/IH/ihtIH/WSIHW000/325/20932/230636.html?d=dmtContent; http://www.cnn.com/2003/HEALTH/diet.fitness/10/28/vitamin.D.ap/; http://www.umm.edu/patiented/articles/what_sunscreen_guidelines_000020_4.htm; American Journal of Clinical Nutrition, December 2004, 80 (Supplement 6):1678S-88S; and Archives of Dermatology, December 1988, pages 1802-1804).

On the other side of this argument are proponents for sun avoidance (myself included) who encourage maintaining adequate levels of vitamin D through dietary sources and supplements without skimping on the sunscreen because sunscreen does not block the amount of UVB radiation needed to help the body manufacture vitamin D.

An article reprinted in PCI Journal, Volume 12, Number 4, November 2004, refers to comments by dermatologist Darrell S. Rigel, M.D., clinical professor, New York University Medical Center in New York City. He reports that as someone who sees and treats skin cancer patients on a daily basis, it is appalling to him that anyone in good conscience would claim that intentional sun exposure, regardless of length of time, is beneficial. It is a fact that skin cancer rates are rising and solid science supports the daily application of sunscreen as the best defense against the damaging effects of sunlight. The same article also mentioned a 1997 study published in the Journal of the National Cancer Institute. It concerned patients with xeroderma pigmentosa (a disease that causes multiple skin cancers in persons exposed to even small amounts of UV radiation). The study demonstrated that these patients, despite avid sun avoidance and constant UV protection, still had normal levels of vitamin D over a period of several years. There is also the issue that no sunscreen, regardless of active ingredients or how often or liberally it is applied, can provide 100% protection from UV radiation. The tiny amount of UVB light that sunscreens do not shield is enough to begin the synthesis of vitamin D (though depending on your skin color and climate, supplemental vitamin D will likely still be necessary).

Further, several large, controlled studies have shown that vitamin D deficiency does not result from ongoing regular sunscreen use. Vitamin D supplementation is a good idea because most people’s diets are naturally deficient in it, not to mention as we age our bodies’ ability to produce vitamin D naturally diminishes due to the decrease in 7-dehydrocholesterol (a component in skin that begins the conversion process for vitamin D) (Sources: The Journal of the American Osteopathic Association, Volume 103, Number 8, August 2003, pages 3-4; American Journal of Clinical Dermatology, March 2002, pages 185-191; Dermatology, January 2001, pages 27-30; British Medical Journal, October 1999, page 1066). Before beginning any new vitamin supplement program, make sure to consult your physician.

 

ON BLAMING CHEMICAL SUNSCREENS FOR THE RISE IN SKIN CANCER RATES  
 (NOTE THE MENTION OF THE DEPLETION OF THE OZONE LAYER)

                  Source: http://www.cosmeticscop.com/bulletin/091406-full.htm#2

Dear Paula,
According to one of the cosmetics catalogs I received in the mail, "despite decades of sunscreen use in this country, melanoma and other skin cancers are on the rise. Recent medical research indicates this is due more to the increased use of traditional sunscreens (with all their toxic chemicals) than to the depletion of the ozone layer. Birth defects, lower sperm counts, and a plethora of other medical problems are also now being linked to the ingredients found in typical sunscreens." Huh? Why haven't I heard about this "research" before? Paula, I trust your opinion in these matters. Have you heard anything about the dangers of chemical sunscreens?

Kim, via email

Dear Kim,
I have written about this issue before but it is easy to have missed all that. What I find so disturbing about this is that such misleading, disingenuous information is used by companies to sell their products. Scare tactics definitely don't help the consumer, but they do benefit a company whose major selling point is that everyone else's products are hurting your skin except theirs. First, note that the information you cited is not sourced; rather it's just some nebulous reference to medical research. Without a source who knows what that means?

I, too, have seen random comments concluding that the rise in skin cancer over the past 30 to 40 years is related to sunscreens. Well, think about it. Before the 1960s, no one used sunscreen, even when they were at the beach and exposed to the sun all day; thus, you could think that it must be the use of sunscreens that is causing the problems. After all, weren't the beaches crowded in the 1930s and '40s, and no one was using sunscreen then either, and yet there were very few reported incidences of skin cancer during that period? Beaches were crowded at that time because that's when tanning became fashionable (Source: Journal of Aesthetic Science, May 1998, pages 6–7). But remember, the effects of sun damage take at least 30 to 40 years to show up on skin, so that's why the occurrence of skin cancer began rising precipitously in the ‘60s and '70s.

Many people have also misinterpreted an epidemiological study done by Sloan-Kettering that found regular use of sunscreen between 1975 and 1995 corresponded with increased risk of skin cancer. While that initially sounds like it is related to sunscreen ingredients, the issue had more to do with the way sunscreens had been formulated in previous decades. Before 1995, sunscreens rarely, if ever, contained ingredients that could filter UVA rays, which are considered to be the sun's more dangerous, cancer-causing radiation. Sunscreens at that time were developed to protect skin only from sunburn, which is caused by UVB rays. So using sunscreens with UVB protection (and minimal to no UVA protection) meant you could stay out in the sun longer without burning, but it also meant you would be receiving intense UVA damage. People who didn't use sunscreen (to protect themselves from sunburn) tended to keep out of the sun more, thus reducing their exposure to both UVA and UVB rays, and as a result saved their skin. The invisible, intense damage caused by UVA rays is why the use of sunscreens (which at that time protected the skin only from UVB rays) was correlated with increased risk of melanoma. Only recently have sunscreens begun to use UVA filters along with UVB filters. Even Dr. Marianne Berwick, author of Sloan-Kettering's study, didn't say that people shouldn't use sunscreen.

Also complicating matters is research showing that some sunscreen ingredients have estrogenic effects (Source: Toxicology and Applied Pharmacology, July 2006, pages 1–7, and February 2006, pages 246–256). This research has also been taken out of context because these studies were done either in vitro (test tubes) or on animals. How does feeding mice or rats pure octyl methoxycinnamate or benzophenone translate into a cancer risk for humans using it topically at infinitely smaller concentrations?

I'll also bet the catalog you received didn't mention that the European Union's Scientific Committee on Cosmetic and Non-Food Products conducted several evaluations of the research on octyl methxoxycinnamate and other UV light-filtering ingredients. Their conclusion? UV filters "have [extremely] low estrogenic activity with no risk to human health." The Committee reaffirmed their recommendation of daily use of sunscreen to "protect humans from excessive exposure to sunlight" (Source: Environmental Health Perspective, 2001, pages 239–244).

It is true that melanoma (the deadliest form of skin cancer) rates are on the rise. According to a report in the June 2006 issue of Cosmetics & Toiletries magazine, the death rate from melanoma in the United States rises 4% every year, with 1.5 million new cases reported annually. But, there is no research showing that the 4% increase has anything to do with the active ingredients in sunscreens. Instead, research and controlled population studies have shown that it has everything to do with consumers not applying sunscreen liberally, not reapplying it at regular intervals during long days outdoors, not using sunscreens that supply sufficient UVA protection, and the depletion of the atmosphere's protective ozone layer (Sources: Journal of Surgical Oncology, July 2004, pages 236–245; Annals of Epidemiology, July 2003, pages 395–404; Photochemistry and Photobiology, July 2001, pages 61–63; and Archives of Dermatology, October 2002, pages 1319–1325). It is theorized that the present frequency of new melanoma cases has nothing to do with the ingredients of the broad-spectrum sunscreens that are now available. Rather, it has to do with the fact that these sunscreens have been available for only a short time relative to the 40-year development period for melanoma.

For some, it is easier to blame strange-sounding chemicals in active ingredients for the increasing skin-cancer rates than to honestly evaluate their sun behavior and the amount of time they spend in the sun without proper sunscreen protection. It is true that the active ingredients used in sunscreens are not completely without negative side effects. However, to view them as dangerous rather than as essential to preserving the health and appearance of your skin is a far bigger error because the amount of cumulative DNA damage unprotected skin receives from sun exposure leads to a host of problems, including those with potentially fatal results.